Application of membrane filters for spectrophotometric determination of cationic surfactants in river water and sediment.

Cationic surfactant (CS+) in urban river water and sediment was extracted and determined spectrophotometrically with 2 membrane filters. The CS+ in the water samples, mostly in the form of an ion associate with the coexisting anionic surfactant (AS), was collected on a polytetrafluoroethylene (PTFE) membrane filter and eluted with methanol. Bromphenol blue (BPB), hydrochloric acid, and water were added to the methanol solution successively, and the mixed solution was filtered through a mixed cellulose ester membrane filter. The CS+-BPB- ion associate, formed by a counter ion exchange, was collected on the filter and dissolved into N,N-dimethylformamide (DMF) together with the mixed cellulose ester membrane filter. After addition of 2 drops of triethanolamine, the absorbance of the DMF solution was measured. The CS+ in sediment samples was extracted with methanol by ultrasonic irradiation; the methanol solution was then passed through a PTFE membrane filter and evaporated to dryness. The CS+ was redissolved in a small amount of methanol. For water samples, recoveries and relative standard deviations for 0.30 microM benzyldimethyl-tetradecylammonium ion, a standard material, were > or =93 and < or =5%, with a detection limit of 0.02 microM. Concentrations of CS+ in sediments were much higher than those in water samples, indicating that CS+ is adsorbed on the surface of the sediment.     

A Novel Fabrication Technique of Long Period Fiber Gratings Using a Holographic Optical Element

We develop a new flexible and precise ultraviolet exposure technique to fabricate a long period fiber grating using a computer-generated holographic optical element (HOE). The HOE can generate a striped beam pattern with about a 300 #x03BC;m period from a KrF excimer laser. This method offers (1) ease in varying the grating period and (2) grating period precision. We achieve a grating period within an accuracy of #x00B1;0.04 #x03BC;m. This means that the peak wavelength can be controlled within an accuracy of #x00B1;0.2nm with an operating wavelength of 1.55 #x03BC;m.This paper was originally presented at the 2nd International Conference on Optical Design and Fabrication, ODF2000 which was held on November 15-17, 2000 at the International Conference Center, Tokyo, Waseda University, Japan.     

Critical condition of inner cylinder radius for sustaining rotating detonation waves in rotating detonation engine thruster

We describe the critical condition necessary for the inner cylinder radius of a rotating detonation engine (RDE) used for in-space rocket propulsion to sustain adequate thruster performance. Using gaseous C₂H₄ and O₂ as the propellant, we measured thrust and impulse of the RDE experimentally, varying in the inner cylinder radius r_i from 31 mm (typical annular configuration) to 0 (no-inner-cylinder configuration), while keeping the outer cylinder radius (r_o = 39 mm) and propellant injector position (r_inj = 35 mm) constant. In the experiments, we also performed high-speed imaging of self-luminescence in the combustion chamber and engine plume. In the case of relatively large inner cylinder radii (r_i = 23 and 31 mm), rotating detonation waves in the combustion chamber attached to the inner cylinder surface, whereas for relatively small inner cylinder radii (r_i = 0, 9, and 15 mm), rotating detonation waves were observed to detach from the inner cylinder surface. In these small inner radii cases, strong chemical luminescence was observed in the plume, probably due to the existence of soot. On the other hand, for cases where r_i = 15, 23, and 31 mm, the specific impulses were greater than 80% of the ideal value at correct expansion. Meanwhile, for cases r_i = 0 and 9 mm, the specific impulses were below 80% of the ideal expansion value. This was considered to be due to the imperfect detonation combustion (deflagration combustion) observed in small inner cylinder radius cases. Our results suggest that in our experimental conditions, r_i = 15 mm was close to the critical condition for sustaining rotating detonation in a suitable state for efficient thrust generation. This condition in the inner cylinder radius corresponds to a condition in the reduced unburned layer height of 4.5–6.5.     

Multi-frame visualization for detonation wave diffraction

When a detonation wave emerges from a tube into unconfined space filled with a gas mixture, detonation wave diffraction occurs due to abrupt changes in the cross-sectional area. In the present study, we focused on the local explosion in reinitiation and propagation of a transverse detonation wave by performing comprehensive and direct observation with high time resolution visualization in a two-dimensional rectangular channel. Using the visualization methods of shadowgraph and multi-frame, short-time, open-shutter photography, we determined where the wall reflection point is generated, and also determined where the bright point is originated by the local explosion, and investigated the effects of the deviation angle and initial pressure of the gas mixture. We found that the reinitiation of detonation had two modes that were determined by the deviation angle of the channel. If the deviation angle was less than or equal to 30\(^{\circ }\), the local explosion of reinitiation might occur in the vicinity of the channel wall, and if the deviation angle was greater than or equal to 60\(^{\circ }\), the local explosion might originate on the upper side of the tube exit. With a deviation angle greater than 60\(^{\circ }\), the position of the wall reflection point depended on the cell width, so the radial distance of the wall reflection point from the apex of the tube exit was about 12 times the cell width. Similarly, the bright point (local explosion point) was located a distance of about 11 times the cell width from the apex of the tube exit, with a circumferential angle of 48\(^{\circ }\).